The Reactivity Series and Extraction of Metals
Learning about the reactivity series and how it determines metal extraction methods.
Core concept
Extraction methods must match a metal's position in the reactivity series because more reactive metals form more stable compounds, requiring more energy-intensive extraction. For example, aluminium, despite being fairly reactive, is extracted by electrolysis (Hall-Héroult process) since carbon reduction is insufficient for its strongly bonded ore, while iron ore can be reduced using carbon in a blast furnace because iron is less reactive and its oxide bonds are weaker.
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Quick notes
• The reactivity series ranks metals from most to least reactive.
• Highly reactive metals (Na, K, Ca) are extracted using electrolysis.
• Moderately reactive metals (Fe, Zn) are extracted using carbon reduction.
• Unreactive metals (Au, Ag) are often found in their free (uncombined) state in nature.